Analisis Studi Literatur Mengenai Dampak Doping terhadap Peningkatan Kinerja Material Termoelektrik Fe₂CrAl

Affan Shoffani Adam; Dianta Gintig

doi:10.55681/armada.v4i10.4188

Authors

Affan Shoffani Adam Program Studi Magister Teknik Mesin, Universitas Mercu Buana, Indonesia
Dianta Gintig Program Studi Magister Teknik Mesin, Universitas Mercu Buana, Indonesia

DOI:

https://doi.org/10.55681/armada.v4i10.4188

Keywords:

Material Termoelektrik, Fe₂Cral Full-Heusler, Doping, Sifat Termoelektrik, Konduktivitas Termal, Konversi Energi

Abstract

Material termoelektrik full-Heusler Fe₂CrAl merupakan kandidat potensial untuk teknologi konversi energi karena memiliki stabilitas termal tinggi, biaya produksi rendah, dan ketersediaan unsur penyusun yang melimpah. Namun, kinerja Fe₂CrAl murni masih terbatas akibat tingginya konduktivitas termal kisi dan konsentrasi pembawa muatan yang belum optimal. Salah satu pendekatan untuk meningkatkan performanya adalah melalui proses doping. Artikel ini bertujuan mengkaji pengaruh doping Sn, Si, Ti, Ni, dan Co terhadap sifat struktur, elektronik, dan termoelektrik Fe₂CrAl berdasarkan literatur tahun 2020–2026 menggunakan metode Systematic Literature Review (SLR). Hasil kajian menunjukkan bahwa doping Si meningkatkan stabilitas struktur dan konduktivitas listrik, sedangkan Ti memengaruhi struktur pita energi serta koefisien Seebeck. Doping Ni dan Co berpengaruh terhadap transport elektron dan sifat magnetik, tetapi dapat menyebabkan keseimbangan antara konduktivitas listrik dan koefisien Seebeck. Doping Sn menunjukkan potensi besar melalui penurunan konduktivitas termal dan optimasi struktur elektronik. Kajian ini menunjukkan perlunya penelitian lanjutan terkait doping Sn untuk meningkatkan efisiensi termoelektrik Fe₂CrAl.

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References

Abdullah, H., Shuwanto, H., Astarini, N. A., Lie, J., Ginting, R. T., Tsai, M., Shih, S., & Sillanp, M. (2025). A Brief Review of Emerging Strategies in Designing Interfacial Solar Steam Generation for Desalination , Water Purification , Power Generation , and Sea Farming. https://doi.org/10.1021/acsaem.4c03384.

Adv, M., Wang, H., Gurunathan, R., & Fu, C. (2022). Materials Advances Thermoelectric transport effects beyond single parabolic band and acoustic. November 2021. https://doi.org/10.1039/d1ma00780g.

Alawiyyah, M., Vora-ud, A., Thaowankeaw, S., Seetawan, T., & Suweni, M. (2020). Pengaruh Variasi Temperatur Uji ZEM-3 pada Properti Termoelektrik Lapisan Tipis Ti- doped ZnO. 9(2), 2–7.

Andersen, H., & Angeles, L. (n.d.). The Western South Slavic Contrast Sn . sah-ni-ti I / SC sah-nu-ti.

Andrade, V. M., Checca, N. R., Paula, V. G. De, Pirota, K. R., Rossi, A. L., Garcia, F., Vovk, A., Bunyaev, S. A., & Kakazei, G. N. (2023). by pulsed laser deposition for magnonic. June 2012. https://doi.org/10.1063/5.0151291.

Andrade, V. M., Checca, N. R., de Paula, V. G., Pirota, K. R., Rossi, A. L., Garcia, F., ... & Kakazei, G. N. (2023). Full Heusler Fe2CrAl nanogranular films produced by pulsed laser deposition for magnonic applications. Journal of Applied Physics, 134(2).

Ахонін, С. В., Северин, А. Ю., Єрохін, О. Г., Іщук, Ю. Т., Нан, Є. О. П., & Малевича, К. (2026). Дослідження процесів випаровування легуючих елементів при епп жароміцних титанових сплавів системи легування Ti – Al – Z r – Sn – M o – Nb – S i. 19–26.

Bahan, S., & Ramah, T. (2025). Optimalisasi Konduktivitas Termal Beton Berpori Melalui Inovasi Material Berbasis Abu Sekam Padi Dan Serat Kelapa Sebagai Bahan Tambah Ramah Lingkungan Irene Vista Simanjuntak 1 , Sudarno P Tampubolon 2 , Pinondang Simanjuntak 3. 6(1), 47–57.

Bahiense, A. V., Ponciano, V. M., Eduardo, C., Ribeiro, G., Xavier, G. D. C., Possamai, V., & Sagrillo, D. (2024). Development Of A Diamond Composite In The Ni-Co-Fe 3 P-Sn-Wc System Via Free Sintering For Use In Multi-Find Diamond Pearls Mateus Valentim Simmer Sopeletto 1. 1–21.

Benvenuto, D., Giovannetti, M., Ciccozzi, A., Spoto, S., Angeletti, S., & Ciccozzi, M. (2020).Accepted Article Accepted Article Accepted Article Accepted Article. Journal of Medical Virology, Ii, 0–3. https://doi.org/10.1002/cnma.202300020.

Chandra, S. A., Suherman, M. S., Tjahjono, A., & Roberto, R. (2024). Pembuatan Paduan Intermetalik Mg 2 Si Dengan Doping Bismuth Sebagai Material Termoelektrik Synthesis of Bismuth Doped Mg 2 Si Intermetallic Alloy as a Thermoelectric Material. 9, 146–152.

Chatterjee, S., Giri, S., Majumdar, S., Dutta, P., Singha, P., & Banerjee, A. (n.d.). Observation of Griffiths-like phase in the quaternary Heusler compound NiFeTiSn.

Chiu, K., & Lee, P. (2022). Solid-Liquid Interdiffusion Bonding between Ti / Ni / Ag / Sn Backside Metallized Si Chips and Cu / Al 2 O 3 - DBC Substrates with Au / Pd / Ni Surface Finish. 8, 1–7. https://doi.org/10.11159/ijmmme.2022.001.

Compounds, I., Al, M. Y., Mn, Z. Y. V, Al, Z., & Irkhin, V. Y. (2023). Magnetic States and Electronic Properties of Manganese-Based.

De Vito, S., Del Giudice, A., & Di Francia, G. (2024). Electric Transmission and Distribution Network Air Pollution. Sensors, 24(2). https://doi.org/10.3390/s24020587

Dergisi, F. B., & Ahiska, R. (2024). Termoelektrik Kriyo İğne Termoelektrik Kriyo İğne. https://doi.org/10.29109/gujsc.1448682.

Diki, M., Hadi, C. F., Lestari, R. F., & Nalandari, R. (2022). Pemanfaatan Termoelektrik Sebagai Sumber Energi Terbarukan. 04(01), 23–25.

Emadi, F., Vuorinen, V., Mertin, S., & Widell, K. (2022). Microstructural and mechanical characterization of Cu/Sn SLID bonding utilizing Co as contact metallization layer. Journal of Alloys and Compounds, 929, 167228. https://doi.org/10.1016/j.jallcom.2022.167228.

Fibers, S. F., & Ibrahim, O. M. (2022). The Microstructure Formation of a Protective Oxide-Scale Layer.

Fichtner, M., Edström, K., Ayerbe, E., Berecibar, M., Bhowmik, A., Castelli, I. E., Clark, S., Dominko, R., Erakca, M., Franco, A. A., Grimaud, A., Horstmann, B., Latz, A., Lorrmann, H., Meeus, M., Narayan, R., Pammer, F., Ruhland, J., Stein, H., … Weil, M. (2021). Rechargeable Batteries of the Future — The State of the Art from a BATTERY 2030 + Perspective. 2102904. https://doi.org/10.1002/aenm.202102904.

Fitriyani, V., Sugihartono, I., & Prayitno, T. B. (2024). Investigasi Sifat Termoelektrik Pada Material Zno Wurtzite : Pendekatan Berbasis Density Functional Theory. XIII, 114–118.

Fitri, M., Mahzan, S., & Anggara, F. (2020). The mechanical properties requirement for polymer composite automotive parts-a review. International Journal of Advanced Technology in Mechanical, Mechatronics and Materials, 1(3), 125-133.

Garmroudi, F., Parzer, M., Mori, T., & Bauer, E. (2025). Recent progress in Fe- and Ru-based full-Heusler bulk thermoelectrics. Science and Technology of Advanced Materials, 26(1). https://doi.org/10.1080/14686996.2025.2517537.

Generator, T., Niu, W., & Cao, X. (2023). Thermoelectric Field Analysis of Trapezoidal Thermoelectric Generator Based on the Explicit Analytical Solution of Annular.

Gharaibeh, M., Almahmoud, A., Almahmoud, A., & Obeidat, A. (2025). Mechanical , structural , electronic , magnetic , and thermomagnetic properties of the full-Heusler Fe 2 MnAs 1 − x Si x alloy using DFT and Monte Carlo simulation. 1–21.

Ghosh, S., Ziolkowski, P., Oppitz, G., Nguyen, H. D., Bourgès, C., Hattori, Y., Riss, A., Steyrer, S., Rogl, G., Rogl, P., Scha, E., Kawamoto, N., Müller, E., Bauer, E., Boor, J. De, & Mori, T. (2025). Decoupled charge and heat transport in Fe 2 VAl composite thermoelectrics with topological-insulating grain boundary networks. 1–9. https://doi.org/10.1038/s41467-025-57250-6

Ginting, D., Ginting, C. L., Tarigan, K., Mashadi, M., Yunasfi, Y., Sudiro, T., ... & Rhyee, J. S. (2026). Enhanced thermoelectric performance in Fe2CrAl1− 2 x Ni x Sn x Heusler alloys through co-doping and electronic structure optimization. Journal of Materials Science, 1-15.

Gu, W., Zhang, Y., Guo, J., Cai, J., Zhu, Y., & Jü, F. (n.d.). Realizing high thermoelectric performance in n -type SnSe polycrystals via ( Pb , Br ) co-doping and multi-nanoprecipitates synergy 2 . Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons and Peter Keywords : 1–26.

Gurtaran, M., Zhang, Z., & Li, X. (2025). Characterisation of Electro-Brush Plated Nickel Coatings on P-Type ( Zr , Ti ) Co ( Sn , Sb ) Half-Heusler Thermoelectric Materials for Stable Contact Layers. 1–16.

Gurtaran, M., Zhang, Z., Li, X., & Dong, H. (2024a). Cyclic oxidation behaviour of N-type ( Zr , Ti ) Ni ( Sn , Sb ) and P-type ( Zr , Ti ) Co ( Sn , Sb ) thermoelectric materials. 30(April), 7476–7484.

Gurtaran, M., Zhang, Z., Li, X., & Dong, H. (2024b). Developing advanced CrSi coatings for combatting surface degradation of N-type ( Zr , Ti ) Ni ( Sn , Sb ) and P-type ( Zr , Ti ) Co ( Sn , Sb ) half Heusler thermoelectric materials. Journal of Materials Research and Technology, 32(July), 3288–3301. https://doi.org/10.1016/j.jmrt.2024.08.169.

Hilal, А., & Slamgazhy, A. (2023). Sustaining Print Media in the Contemporary Era: a case study of Afghanistan. BULLETIN of L.N. Gumilyov Eurasian National University. Journalism Series, 144(3), 52–59. https://doi.org/10.32523/2616-7174-2023-144-3-52-59.

Hou, B., Guo, Y., Yang, Q., Tang, L., Shi, Y., Gao, J., Pan, Y., Hong, M., Dinh, T., Wang, H., Chen, Z., & Song, P. (2025). Mechanism-Guided Thermoelectric Strategies for Smart Fire Prevention. 2508628, 1–22. https://doi.org/10.1002/adma.202508628.

Huang, H., & Tung, J. (2022). A fi rst-principles study on the effect of Cr , Mn , and Co substitution on Fe-based normal- and inverse-Heusler 3 ; Y = Cr , Mn , Co ; Z = Al , Ga , Si ). September, 1–15. https://doi.org/10.3389/fphy.2022.975780.

Ibrahim, O. M., & Naji, L. Ben. (2021). Multistage heat treatment and the development of a protective oxide ‑ scale layer on the surface of FeCrAl sintered ‑ metal ‑ fibers. Scientific Reports, 0123456789, 1–15. https://doi.org/10.1038/s41598-020-80888-9.

In-situ synthesis of Cr 2 AlC coating by plasma transferred arc cladding. (n.d.). 1–19.

Jin, Y., & Guo, J. (2024). XB 2 Bi 2 ( X = Si , Ge , Sn , Pb ): Penta-Atomic Planar Tetracoordinate Si / Ge / Sn / Pb Clusters with 20 Valence Electrons. 2.

Journal, P. E. (2025). No Title. 8.

Kamble, A. S., & Kaushik, S. D. (2025). Scrutinizing structural and magnetic properties of Fe2CrAl Heusler compound. Next Materials, 8, 100885.

Kumar, P. (2026). Electrochemical Behavior of Flame-Sprayed Sc-Doped AlCoCrFeMo High-Entropy Alloy Coatings in 3 . 5 % Sodium Chloride Solution. 1–17. https://doi.org/10.1002/adem.70870

Li, H. H. H. B., Zhang, F. F., Werf, W. Van Der, Sakai, H., Murphy, J., Riley, J. P., BADU-APRAKU, B., HUNTER, R. B., TOLLENAAR, M., Joergensen and Mueller, 1996, Bharati, K., Mohanty, S. R., Singh, D. P., Rao, V. R., Adhya, T. K., Andrews, S. S., Karlen, D. L., Mitchell, J. P., Chen, M. Y., …

Marchenkov, V. V, & Irkhin, V. Y. (n.d.). Half-metallic Ferromagnets , Spin Gapless Semiconductors , and Topological Semimetals Based on Heusler Alloys. 1–42.

Marti, C. A., Rodrigo, M. A., & Sir, I. (2023). Applied Catalysis B : Environmental A critical review on latest innovations and future challenges of electrochemical technology for the abatement of organics in water. 328(July 2022). https://doi.org/10.1016/j.apcatb.2023.122430.

Mensah-darkwa, K., Ocaya, R. O., Al-sehemi, A. G., Yeboah, D., Dere, A., Al-ghamdi, A. A., Gupta, R. K., & Yakuphanoğlu, F. (2023). Physica B : Condensed Matter Optoelectronic enhancement of ZnO / p-Si Schottky barrier photodiodes by ( Sn , Ti ) co-doping. Physica B: Condensed Matter, 667(July), 415155. https://doi.org/10.1016/j.physb.2023.415155.

Mohan, L., Kumar, S., Singh, A., & Sharma, D. (2020). Structural , Electronic , Optical And Magnetic Properties Of Co 2 CrZ ( Z = Al , Bi , Ge , Si ) HEUSLER COMPOUNDS. 80. https://doi.org/10.26565/2312-4334-2020-2-05.

Moreno, J. J. G., Cao, J., Fronzi, M., & Assadi, M. H. N. (2020). A review of recent progress in thermoelectric materials through computational methods. Materials for Renewable and Sustainable Energy, 9(3), 1–22. https://doi.org/10.1007/s40243-020-00175-5.

Ojha, H., Nightingale, A. J., Gonda, N., Muok, B. O., Eriksen, S., Khatri, D., & Paudel, D. (2022). Transforming environmental governance: critical action intellectuals and their praxis in the field. Sustainability Science, 17(2), 621–635. https://doi.org/10.1007/s11625-022-01108-z.

Parray, R. A., & Ravichandran, K. (2023). Structural, thermal, electrical and magnetic properties of Fe2CrAl FulHeusler alloy prepared by ball milling. Physica B: Condensed Matter, 653, 414665.

Parzer, M., Garmroudi, F., Riss, A., Reticcioli, M., Podloucky, R., Stöger-pollach, M., Constable, E., Pustogow, A., Mori, T., & Bauer, E. (2024). Semiconducting Heusler Compounds beyond the Slater-Pauling Rule. 033006, 1–17. https://doi.org/10.1103/PRXEnergy.3.033006.

Pb, R. (2020). Conventional Solvent Oxidizes Sn(II) in Perovskite Inks. Ii, 1153–1155. https://doi.org/10.1021/acsenergylett.0c00402.

Reviewed, P. (2021). Issn:2277-7881; i. 816(8), 109–113.

RGO / SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel , Yapısal ve Yüzeysel Değerlendirmesi Electrical , Structural , Surface Evaluation Depends on the Different Deposition Temperature of rGO / SnSbS Nanocomposites. (2022).

Rokhim, A. A., & Endahwati, L. (2023). Pemanfaatan Energi panas menggunakan Termoelektrik Generator dengan Variasi Peltier. 14(1), 19–23.

Saha, R., Srinivas, V., & Venimadhav, A. (2012). Observation of magnetic cluster phase above Curie temperature in Fe2CrAl Heusler alloy. Journal of magnetism and magnetic materials, 324(7), 1296-1304.

Si, T. X. H. X., Planar, P. C., Li, Y., Bai, L., & Guo, J. (2023). molecules.

Skotnicova, K., Jurica, J., Zivotsky, O., Cegan, T., Hrabovska, K., Matejka, V., Zla, S., Kawulokova, M., & Chrobak, A. (2025). Preparation and Physical Properties of Quaternary β -Mn Structures.

Structural and Magnetic Properties of Fe 2 CrAl Heusler Alloy. (2023). 6283, 400085.

Sun, H. C., Huang, Y. C., & Huang, C. M. (2012). A review of dissolved gas analysis in power transformers. Energy Procedia, 14(2011), 1220–1225. https://doi.org/10.1016/j.egypro.2011.12.1079.

Te, G., Te, S., & Kəsİklərİ, P. (2026). -Te formullu (A. 295–304.

Trends, D. (2023). A Review of Cu–Ni–Sn Alloys: Processing, Microstructure, Properties, and Developing Trends.

Umetsu, R. Y., Morimoto, N., Nagasako, M., Kainuma, R., & Kanomata, T. (2012). Annealing temperature dependence of crystal structures and magnetic properties of Fe2CrAl and Fe2CrGa Heusler alloys. Journal of alloys and compounds, 528, 34-39.

Omar, A., Börrnert, F., Richter, M., Trinckauf, J., Heinsch, F., Blum, C. G. F., ... & Wurmehl, S. (2025). Material design toward a thermodynamically stable Co–Cr–Fe–Al Heusler-type phase. APL Materials, 13(5).

Wahyudin, A. R., Raihan, A., Adrian, M. F., Agustian, R., Darian, M. A., Ramadhan A, M. F., Paundra, F., & Ito, Y. (2024). Analisis Dan Perawatan Pada Water Treatment Plant (Wtp) Pltu X. Perwira Journal of Science & Engineering, 4(2), 86–93. https://doi.org/10.54199/pjse.v4i2.306

Susanto, A., Yusuf, S. Q., Hamid, A., Wahyudi, H., & Subekti, S. (2019). Implementation of frequency response function on tapper bearing maintenance. Sinergi, 23(2), 132-138.

Wei, X., Liu, X., Sun, H., & Zhang, Y. (n.d.). Pr ep rin ot pe er r Pr ep rin ot pe er ed.

Wei, X., Liu, X., Zhang, J., Zhang, Y., & Tao, X. (n.d.). iScience. https://doi.org/10.1016/j.isci.2024.111257.

Yadav, K., & Mukherjee, K. (n.d.). Effect of partial substitution of iso-valent Mo at Cr-site on electronic structure and physical properties of Fe 2 CrAl. 1–22.

Yadav, K., Ranaut, D., & Mukherjee, K. (n.d.). Unconventional critical behaviour in weak ferromagnets Fe 2-x Mn x CrAl. 1–15.

Yadav, K., Sharma, M. K., Singh, S., & Mukherjee, K. (n.d.). Exotic magnetic behaviour and evidence of cluster glass and Griffiths like phase in Heusler alloys Fe 2-x Mn x CrAl ( 0 ≤ x ≤ 1 ).

Yadav, K., Singh, S., Muthuswamy, O., & Takeuchi, T. (1905). Anomalous dependence of thermoelectric parameters on carrier concentration and electronic structure in Mn-substituted Fe 2 CrAl Heusler alloy Anomalous dependence of thermoelectric parameters on carrier concentration and electronic structure in Mn-substituted Fe 2 CrAl Heusler alloy.

Yang, D., Shi, X., Li, M., Nisar, M., Mansoor, A., Chen, S., Chen, Y., Li, F., Ma, H., Liang, G. X., Zhang, X., Liu, W., Fan, P., Zheng, Z., & Chen, Z. (2024). Flexible power generators by Ag 2 Se thin fi lms with record-high thermoelectric performance. 1–11. https://doi.org/10.1038/s41467-024-45092-7.

Yang, S., Qiu, P., Chen, L., & Shi, X. (2021). Recent Developments in Flexible Thermoelectric Devices. 2100005. https://doi.org/10.1002/smsc.202100005.

Yang, Y., Li, S., Cui, Z., Li, Z., Li, Y., & Lei, Q. (2021). Microstructure and properties of high‐strength Cu–Ni–Si–(Ti) alloys. 40, 3251–3260. https://doi.org/10.1007/s12598-020-01699-5.

Żak, K. M., Pakieła, W., Łukowiec, D., Bajorek, A., Gębara, P., & Szakál, A. (2022). Structure and selected properties of Al – Cr – Fe alloys with the presence of structurally complex alloy phases. Scientific Reports, 0123456789, 1–12. https://doi.org/10.1038/s41598-022-17870-0.

Zhang, C., Shi, X., Liu, Q., & Chen, Z. (2024). Hydrogel-Based Functional Materials for Thermoelectric Applications : Progress and Perspectives. 2410127, 1–27. https://doi.org/10.1002/adfm.202410127.

Zhou, L., Danilov, D. L., Qiao, F., Wang, J., Li, H., Eichel, R., & Notten, P. H. L. (2022). Sulfur Reduction Reaction in Lithium – Sulfur Batteries : Mechanisms , Catalysts , and Characterization. 2202094. https://doi.org/10.1002/aenm.202202094.